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May 20, 2009 | Jim Lane | Comments 0

Researchers find one-step process for converting cellulose to HMF, which can be refined into drop-in renewable fuels

In Washington, researchers at the Pacific Northwest National Laboratory report a new method for converting cellulose in a single-step to the building block HMF, which can thereupon be refined into renewable polyesters, green gasoline or green diesel.

In their research, the team used a combination of copper chloride and chromium chloride at 120 degrees Celsius broke down cellulose without created unneeded by products. The process converted 57 percent of potential sugars in cellulose and recovered 90 percent of the HMF.

“In biomass like wood, corn stover and switchgrass, cellulose is the most abundant polymer that researchers are trying to convert to biofuels and plastics,” said chemist Z. Conrad Zhang, who led the work while at PNNL’s Institute for Interfacial Catalysis.  The process converts cellulose ten times faster than the use of acid to break down cellulose.

The result builds upon earlier work by researchers at the Department of Energy’s Pacific Northwest National Laboratory. In that work, scientists produced HMF from simple sugars derived from cellulose. In this new work, researchers developed a way to bypass the sugar-forming step and go straight from cellulose to HMF.

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